Application of two-dimensional correlation spectroscopy for monitoring the mechanism of reaction between phenyl glycidyl ether (PGE) and metaphenylene diamine (mPDA)
dc.contributor.author | Hollock, Michael R. | |
dc.date.accessioned | 2012-05-21T14:06:14Z | |
dc.date.available | 2012-05-21T14:06:14Z | |
dc.date.graduationmonth | May | en_US |
dc.date.issued | 2012-05-21 | |
dc.date.published | 2012 | en_US |
dc.description.abstract | The curing reaction for the amine epoxy resin system of phenyl glycidyl ether (PGE) with metaphenylene diamine (mPDA) was investigated using two-dimensional correlation spectroscopy in the near-infared region (2DNIR). Synchronous and asynchronous correlation maps were generated using 2Dshige© software. The characteristic NIR band assignments were made, including the identification of new peaks for the O-H combination band in the 4825-4750 cm[superscript]-1 region and the CH stretching vibration overtone at 6018 cm[superscript]-1. Finally, the data suggests the reaction proceeds as follows: the appearance of the OH groups and C-H backbone vibrations occurs before the primary amine reactions and epoxide rings disappear. | en_US |
dc.description.advisor | J.R. Schlup | en_US |
dc.description.degree | Master of Science | en_US |
dc.description.department | Department of Chemical Engineering | en_US |
dc.description.level | Masters | en_US |
dc.identifier.uri | http://hdl.handle.net/2097/13838 | |
dc.publisher | Kansas State University | en |
dc.subject | 2DNIR | en_US |
dc.subject | Near-infrared spectroscopy | en_US |
dc.subject | 2D correlation analysis | en_US |
dc.subject | Epoxy curing | en_US |
dc.subject.umi | Chemical Engineering (0542) | en_US |
dc.title | Application of two-dimensional correlation spectroscopy for monitoring the mechanism of reaction between phenyl glycidyl ether (PGE) and metaphenylene diamine (mPDA) | en_US |
dc.type | Report | en_US |
Files
Original bundle
1 - 3 of 3
Loading...
- Name:
- MichaelHollock2012.pdf
- Size:
- 3.86 MB
- Format:
- Adobe Portable Document Format
- Description:
- Main article
No Thumbnail Available
- Name:
- Data_FuSchlup1993_raw.csv
- Size:
- 1.5 MB
- Format:
- Comma Separated Value
- Description:
- Raw data
No Thumbnail Available
- Name:
- Data_Hollock2012_calculations.xlsx
- Size:
- 1.71 MB
- Format:
- Unknown data format
- Description:
- Calculations
License bundle
1 - 1 of 1
No Thumbnail Available
- Name:
- license.txt
- Size:
- 1.65 KB
- Format:
- Item-specific license agreed upon to submission
- Description: