Concentration fluctuations in fluid mixtures. II.

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dc.contributor.author Mazo, Robert M.
dc.contributor.author Matteoli, Enrico
dc.contributor.author Smith, Paul E.
dc.date.accessioned 2011-08-18T19:36:17Z
dc.date.available 2011-08-18T19:36:17Z
dc.date.issued 2011-08-18
dc.identifier.uri http://hdl.handle.net/2097/12044
dc.description.abstract The method developed in a previous paper [R. Mazo, J. Chem. Phys. 129, 154101 (2008)] for extracting information on the size of relative fluctuations in multicomponent systems is tested on ten binary systems and one ternary system. For the binary systems, it is found that the approximation works well for mole fractions in the range of 0.15–0.85 in most cases. For the ternary case, the method inherently yields less information and is valid only over a more restricted range for the case studied (chloroform-methanol-acetone). It is found that the predicted ratio of number fluctuations is approximately equal to the ratio of molar volumes of the components. en_US
dc.relation.uri http://jcp.aip.org/resource/1/jcpsa6/v130/i23/p234508_s1 en_US
dc.rights Copyright 2009 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. en
dc.subject Fluctuations en_US
dc.subject Liquid mixtures en_US
dc.subject Liquid theory en_US
dc.subject Organic compounds en_US
dc.subject Thermodynamic properties en_US
dc.title Concentration fluctuations in fluid mixtures. II. en_US
dc.type Article (publisher version) en_US
dc.date.published 2009 en_US
dc.citation.doi doi:10.1063/1.3154582 en_US
dc.citation.issue 23 en_US
dc.citation.jtitle Journal of Chemical Physics en_US
dc.citation.volume 130 en_US
dc.contributor.authoreid pesmith en_US

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