Burt, MichaelBoll, RebeccaLee, Jason W. L.Amini, KasraKöckert, HansjochenVallance, ClaireGentleman, Alexander S.Mackenzie, Stuart R.Bari, SadiaBomme, CédricDüsterer, StefanErk, BenjaminManschwetus, BastianMüller, ErlandRompotis, DimitriosSavelyev, EvgenySchirmel, NoraTechert, SimoneTreusch, RolfKüpper, JochenTrippel, SebastianWiese, JossStapelfeldt, Henrikde Miranda, Barbara CunhaGuillemin, RenaudIsmail, IyasJournel, LoïcMarchenko, TatianaPalaudoux, JérômePenent, FrancisPiancastelli, Maria NovellaSimon, MarcTravnikova, OksanaBrausse, FelixGoldsztejn, GildasRouzée, ArnaudGéléoc, MarieGeneaux, RomainRuchon, ThierryUnderwood, JonathanHolland, David M. P.Mereshchenko, Andrey S.Olshin, Pavel K.Johnsson, PerMaclot, SylvainLahl, JanRudenko, ArtemZiaee, FarzanehBrouard, MarkRolles, Daniel2020-06-172020-06-172017-10-17https://hdl.handle.net/2097/40733The dynamics following laser-induced molecular photodissociation of gas-phase CH2BrI at 271.6 nm were investigated by time-resolved Coulomb-explosion imaging using intense near-IR femtosecond laser pulses. The observed delay-dependent photofragment momenta reveal that CH2BrI undergoes C-I cleavage, depositing 65.6% of the available energy into internal product states, and that absorption of a second UV photon breaks the C-Br bond of CH2Br. Simulations confirm that this mechanism is consistent with previous data recorded at 248 nm, demonstrating the sensitivity of Coulomb-explosion imaging as a real-time probe of chemical dynamics.This Item is protected by copyright and/or related rights. You are free to use this Item in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s).Optical pumpingPhotodissociationUltrafast phenomenaCoulomb-explosionText