Mariette, C.Guerin, L.Rabiller, P.Chen, Y. S.Bosak, A.Popov, A.Hollingsworth, Mark D.Toudic, B.2016-04-042016-04-042014-09-12http://hdl.handle.net/2097/32259Citation: Mariette, C., Guerin, L., Rabiller, P., Chen, Y. S., Bosak, A., Popov, A., . . . Toudic, B. (2015). The creation of modulated monoclinic aperiodic composites in n-alkane/urea compounds. Zeitschrift Fur Kristallographie, 230(1), 5-11. doi:10.1515/zkri-2014-1773n-Dodecane/urea is a member of the prototype series of n-alkane/urea inclusion compounds. At room temperature, it presents a quasi-one dimensional liquid-like state for the confined guest molecules within the rigid, hexagonal framework of the urea host. At lower temperatures, we report the existence of two other phases. Below T-c=248 K there appears a phase with rank four superspace group P6(1)22(00 gamma), the one typically observed at room temperature in n-alkane/urea compounds with longer guest molecules. A misfit parameter, defined by the ratio gamma=C-h/C-g (C-host/C-guest), is found to be 0.632 +/- 0.005. Below T-c1=123 K, a monoclinic modulated phase is created with a constant shift along c of the guest molecules in adjacent channels. The maximal monoclinic space group for this structure is P12(1)1(alpha 0 gamma). Analogies and differences with n-heptane/urea, which also presents a monoclinic, modulated low-temperature phase, are discussed.This Item is protected by copyright and/or related rights. You are free to use this Item in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s).Alkane/Urea CrystalsAperiodic CrystalsCrystallographic SuperspaceDiffractionPhase TransitionsUrea Inclusion-CompoundsArticle