Kirkwood–Buff theory of four and higher component mixtures

Files

SmithJoCP20084.pdf (219.5 KB)

Date

Authors

Kang, Myungshim

Abstract

Explicit expressions are developed for the chemical potential derivatives, partial molar volumes, and isothermal compressibility of solution mixtures involving four components at finite concentrations using the Kirkwood–Buff theory of solutions. In addition, a general recursion relationship is provided which can be used to generate the chemical potential derivatives for higher component solutions.

Keywords

Chemical potential, Compressibility, Liquid mixtures, Liquid theory, Kirkwood-Buff theory

URI

http://hdl.handle.net/2097/12047

Collections

Chemistry Faculty Research and Publications

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Except where otherwise noted, this item's license is described as This Item is protected by copyright and/or related rights. You are free to use this Item in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s).