Kirkwood–Buff theory of four and higher component mixtures

Date

2011-08-18

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Abstract

Explicit expressions are developed for the chemical potential derivatives, partial molar volumes, and isothermal compressibility of solution mixtures involving four components at finite concentrations using the Kirkwood–Buff theory of solutions. In addition, a general recursion relationship is provided which can be used to generate the chemical potential derivatives for higher component solutions.

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Keywords

Chemical potential, Compressibility, Liquid mixtures, Liquid theory, Kirkwood-Buff theory

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