Probing calculated O-2(+) potential-energy curves with an XUV-IR pump-probe experiment
Date
2015-04-22
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Citation: Corlin, P., Fischer, A., Schonwald, M., Sperl, A., Mizuno, T., Thumm, U., . . . Moshammer, R. (2015). Probing calculated O-2(+) potential-energy curves with an XUV-IR pump-probe experiment. Physical Review A, 91(4), 8. doi:10.1103/PhysRevA.91.043415
We study dissociative photoionization of molecular oxygen in a kinematically complete XUV-IR pump-probe experiment. Detecting charged fragments and photoelectrons in coincidence using a reaction microscope, we observe a pump-probe delay-dependent yield of very low energetic O+ ions which oscillates with a period of 40 fs. This feature is caused by a time-dependent vibrational wave packet in the potential of the binding O-2(+)(a(4)Pi(u))state, which is probed by resonant absorption of a single infrared photon to the weakly repulsive O-2(+)(f(4)Pi(g)) state. By quantitative comparison of the experimental kinetic-energy-release (KER) and quantum-beat (QB) spectra with the results of a coupled-channel simulation, we are able to discriminate between the calculated adiabatic O-2(+) potential-energy curves (PECs) of Marian et al. [Marian, Marian, Peyerimhoff, Hess, Buenker, and Seger, Mol. Phys. 46, 779 (1982)] and Magrakvelidze et al. [Magrakvelidze, Aikens, and Thumm, Phys. Rev. A 86, 023402 (2012)]. In general, we find a good agreement between experimental and simulated KER and QB spectra. However, we could not reproduce all features of the experimental data with these PECs. In contrast, adjusting a Morse potential to the experimental data, most features of the experimental spectra are well reproduced by our simulation. By comparing this Morse potential to theoretically predicted PECs, we demonstrate the sensitivity of our experimental method to small changes in the shape of the binding potential.
We study dissociative photoionization of molecular oxygen in a kinematically complete XUV-IR pump-probe experiment. Detecting charged fragments and photoelectrons in coincidence using a reaction microscope, we observe a pump-probe delay-dependent yield of very low energetic O+ ions which oscillates with a period of 40 fs. This feature is caused by a time-dependent vibrational wave packet in the potential of the binding O-2(+)(a(4)Pi(u))state, which is probed by resonant absorption of a single infrared photon to the weakly repulsive O-2(+)(f(4)Pi(g)) state. By quantitative comparison of the experimental kinetic-energy-release (KER) and quantum-beat (QB) spectra with the results of a coupled-channel simulation, we are able to discriminate between the calculated adiabatic O-2(+) potential-energy curves (PECs) of Marian et al. [Marian, Marian, Peyerimhoff, Hess, Buenker, and Seger, Mol. Phys. 46, 779 (1982)] and Magrakvelidze et al. [Magrakvelidze, Aikens, and Thumm, Phys. Rev. A 86, 023402 (2012)]. In general, we find a good agreement between experimental and simulated KER and QB spectra. However, we could not reproduce all features of the experimental data with these PECs. In contrast, adjusting a Morse potential to the experimental data, most features of the experimental spectra are well reproduced by our simulation. By comparing this Morse potential to theoretically predicted PECs, we demonstrate the sensitivity of our experimental method to small changes in the shape of the binding potential.
Keywords
Cross-Sections, Molecular-Oxygen, Photoionization, Optics, Physics
