Silver (I) coordination chemistry: from 1-D chains to molecular rectangles

K-REx Repository

Show simple item record

dc.contributor.author Abul-Haj, Mohammad
dc.contributor.author Aakeröy, Christer B.
dc.contributor.author Desper, John
dc.date.accessioned 2013-02-15T16:15:20Z
dc.date.available 2013-02-15T16:15:20Z
dc.date.issued 2012-10-17
dc.identifier.uri http://hdl.handle.net/2097/15305
dc.description.abstract A series of silver(I) coordination compounds with the ligand 2-(4-pyridyl)imidazole 4-PyIm has been synthesized and crystallographically characterized in order to explore the role of counter ion, solvent and ligand charge on the resulting supramolecular architectures. With perchlorate and hexaflourophosphate, two iso-structural 1-D coordination-polymers were obtained, but when changing the counter ion to nitrate and using water as solvent, an unusual molecular rectangle composed of four ligands and four Ag(I) ions was obtained, and the assembly was controlled by hydrogen bonding via the anion and water molecules. Finally, when the ligand was deprotonated, the change in the number of binding sites (from two to three) was reflected in an increase in coordination number for the silver ion. en_US
dc.language.iso en_US en_US
dc.relation.uri http://doi.org/10.1039/c2nj40669a en_US
dc.rights This Item is protected by copyright and/or related rights. You are free to use this Item in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s). en_US
dc.rights.uri http://rightsstatements.org/vocab/InC/1.0/
dc.subject Silver(I) en_US
dc.subject 4-PyIm en_US
dc.subject Crystal engineering en_US
dc.subject Supramolecular chemistry en_US
dc.subject Molecular rectangles en_US
dc.title Silver (I) coordination chemistry: from 1-D chains to molecular rectangles en_US
dc.type Article (author version) en_US
dc.date.published 2013 en_US
dc.citation.doi 10.1039/c2nj40669a en_US
dc.citation.epage 211 en_US
dc.citation.issue 1 en_US
dc.citation.jtitle New Journal of Chemistry en_US
dc.citation.spage 204 en_US
dc.citation.volume 37 en_US
dc.contributor.authoreid aakeroy en_US
dc.contributor.authoreid desperj en_US


Files in this item

This item appears in the following Collection(s)

Show simple item record

This Item is protected by copyright and/or related rights. You are free to use this Item in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s). Except where otherwise noted, the use of this item is bound by the following: This Item is protected by copyright and/or related rights. You are free to use this Item in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s).

Search K-REx


Browse

My Account

Statistics








Center for the

Advancement of Digital

Scholarship

cads@k-state.edu