Unambiguous observation of F-atom core-hole localization in CF4 through body-frame photoelectron angular distributions

K-REx Repository

Show simple item record

dc.contributor.author McCurdy, C. W.
dc.contributor.author Rescigno, T. N.
dc.contributor.author Trevisan, C. S.
dc.contributor.author Lucchese, R. R.
dc.contributor.author Gaire, B.
dc.contributor.author Menssen, A.
dc.contributor.author Schöffler, M. S.
dc.contributor.author Gatton, A.
dc.contributor.author Neff, J.
dc.contributor.author Stammer, P. M.
dc.contributor.author Rist, J.
dc.contributor.author Eckart, S.
dc.contributor.author Berry, Ben
dc.contributor.author Severt, T.
dc.contributor.author Sartor, J.
dc.contributor.author Moradmand, A.
dc.contributor.author Jahnke, T.
dc.contributor.author Landers, A. L.
dc.contributor.author Williams, J. B.
dc.contributor.author Ben-Itzhak, Itzhak
dc.contributor.author Dörner, R.
dc.contributor.author Belkacem, A.
dc.contributor.author Weber, T.
dc.date.accessioned 2017-12-12T20:40:58Z
dc.date.available 2017-12-12T20:40:58Z
dc.identifier.uri http://hdl.handle.net/2097/38525
dc.description Citation: McCurdy, C. W., Rescigno, T. N., Trevisan, C. S., Lucchese, R. R., Gaire, B., Menssen, A., . . . Weber, T. (2017). Unambiguous observation of F-atom core-hole localization in CF4 through body-frame photoelectron angular distributions. Physical Review A, 95(1). doi:10.1103/PhysRevA.95.011401
dc.description.abstract A dramatic symmetry breaking in K-shell photoionization of the CF4 molecule in which a core-hole vacancy is created in one of four equivalent fluorine atoms is displayed in the molecular frame angular distribution of the photoelectrons. Observing the photoejected electron in coincidence with an F+ atomic ion after Auger decay is shown to select the dissociation path where the core hole was localized almost exclusively on that atom. A combination of measurements and ab initio calculations of the photoelectron angular distribution in the frame of the recoiling CF3+ and F+ atoms elucidates the underlying physics that derives from the Ne-like valence structure of the F(1s-1) core-excited atom. © 2017 American Physical Society.
dc.relation.uri https://doi.org/10.1103/PhysRevA.95.011401
dc.rights ©2017 American Physical Society. This Item is protected by copyright and/or related rights. You are free to use this Item in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s).
dc.rights.uri https://journals.aps.org/authors/transfer-of-copyright-agreement
dc.subject Atoms
dc.subject Calculations
dc.subject Fluorine
dc.subject Photoelectrons
dc.subject Photons
dc.subject Ab Initio Calculations
dc.title Unambiguous observation of F-atom core-hole localization in CF4 through body-frame photoelectron angular distributions
dc.type Article
dc.date.published 2017
dc.citation.doi 10.1103/PhysRevA.95.011401
dc.citation.issn 2469-9926
dc.citation.issue 1
dc.citation.jtitle Physical Review A
dc.citation.volume 95
dc.contributor.authoreid itzik
dc.contributor.kstate Ben-Itzhak, Itzhak


Files in this item

This item appears in the following Collection(s)

Show simple item record

Search K-REx


Advanced Search

Browse

My Account

Statistics








Center for the

Advancement of Digital

Scholarship

118 Hale Library

Manhattan KS 66506


(785) 532-7444

cads@k-state.edu