An oil-source rock correlation examining the potential of the Chattanooga shale as a source rock for oil within the Spivey-Grabs-Basil Field, Kingman and Harper Counties, Kansas

dc.contributor.authorWall, Meaganen_US
dc.date.accessioned2015-04-23T17:24:42Z
dc.date.available2015-04-23T17:24:42Z
dc.date.graduationmonthMayen_US
dc.date.issued2015-05-01
dc.date.published2015en_US
dc.description.abstractOil production in Kansas has a long history with plays being found on all sides of the state. The source of Kansas’s hydrocarbons has been traditionally thought to be outside the state due to low thermal maturity and the shallow burial of potential source rocks within Kansas. This research addresses the question regarding the source of the oil in Kansas, at least within a small geographic area of roughly 146mi[superscript]2. The Spivey-Grabs-Basil Field has been one of the more successful fields within the state of Kansas since the 1960’s. This field is compartmentalized and offers a natural laboratory in which to conduct the field’s first formal oil-source rock correlation since oils are locked into place. While the main focus of this research relies heavily on pyrolysis and GCMS for biomarker analysis, it also investigates the possibility of using rare earth element (REE) concentrations as a possible fingerprint of organic matter within a source bed. TOC values of the Chattanooga shale samples from the Spivey-Grabs-Basil filed range from 0.75 and 3.95 wt. %, well within productive capacity. Pyrograms show both the potential for additional production, and the likely previous expulsion of hydrocarbons. Biomarker concentration percentages between C[subscript]27, C[subscript]28, and C[subscript]29 steranes, as well as pentacyclic terpane ratios compared between crude oil from the Spivey-Grabs-Basil and the Chattanooga shale show a definite genetic relationship. REE values of the organic fraction of the Chattanooga inversely correlate with those of the crude oils, suggesting fractionation during oil generation. After comparison of results with the Woodford shale in Oklahoma, the conclusion of this study is that the Chattanooga shale which underlies the Spivey-Grabs-Basil oil field of southern Kansas is the probable source rock which generated the oil now being produced.en_US
dc.description.advisorMatthew W. Tottenen_US
dc.description.degreeMaster of Scienceen_US
dc.description.departmentDepartment of Geologyen_US
dc.description.levelMastersen_US
dc.description.sponsorshipPaul and Deana Strunk Graduate Scholarship Gale R. and Linda M. Yarrow Scholarship Totten and Chaudhuri Funden_US
dc.identifier.urihttp://hdl.handle.net/2097/19013
dc.language.isoen_USen_US
dc.publisherKansas State Universityen
dc.subjectBiomarkersen_US
dc.subjectCorrelationen_US
dc.subjectSpivey-Grabs-Basilen_US
dc.subjectRare Earth Elementsen_US
dc.subjectChattanooga shaleen_US
dc.subjectWoodford shaleen_US
dc.subject.umiGeochemistry (0996)en_US
dc.subject.umiGeology (0372)en_US
dc.subject.umiPetroleum Geology (0583)en_US
dc.titleAn oil-source rock correlation examining the potential of the Chattanooga shale as a source rock for oil within the Spivey-Grabs-Basil Field, Kingman and Harper Counties, Kansasen_US
dc.typeThesisen_US

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