Identification of absolute geometries of cis and trans molecular isomers by Coulomb Explosion Imaging
dc.citation.doi | 10.1038/srep38202 | |
dc.citation.issn | 2045-2322 | |
dc.citation.jtitle | Scientific Reports | |
dc.citation.spage | 8 | |
dc.citation.volume | 6 | |
dc.contributor.author | Ablikim, U. | |
dc.contributor.author | Bomme, C. | |
dc.contributor.author | Xiong, H. | |
dc.contributor.author | Savelyev, E. | |
dc.contributor.author | Obaid, R. | |
dc.contributor.author | Kaderiya, B. | |
dc.contributor.author | Augustin, S. | |
dc.contributor.author | Schnorr, K. | |
dc.contributor.author | Dumitriu, I. | |
dc.contributor.author | Osipov, T. | |
dc.contributor.author | Bilodeau, R. | |
dc.contributor.author | Kilcoyne, D. | |
dc.contributor.author | Kumarappan, Vinod | |
dc.contributor.author | Rudenko, Artem | |
dc.contributor.author | Berrah, N. | |
dc.contributor.author | Rolles, Daniel | |
dc.contributor.authoreid | vinodjrm | |
dc.contributor.authoreid | rudenko | |
dc.contributor.authoreid | rolles | |
dc.contributor.kstate | Kumarappan, Vinod | |
dc.contributor.kstate | Rudenko, Artem | |
dc.contributor.kstate | Rolles, Daniel | |
dc.date.accessioned | 2017-12-12T20:40:18Z | |
dc.date.available | 2017-12-12T20:40:18Z | |
dc.date.issued | 2016-12-02 | |
dc.date.published | 2016 | |
dc.description | Citation: Ablikim, U., Bomme, C., Xiong, H., Savelyev, E., Obaid, R., Kaderiya, B., . . . Rolles, D. (2016). Identification of absolute geometries of cis and trans molecular isomers by Coulomb Explosion Imaging. Scientific Reports, 6, 8. doi:10.1038/srep38202 | |
dc.description.abstract | An experimental route to identify and separate geometric isomers by means of coincident Coulomb explosion imaging is presented, allowing isomer-resolved photoionization studies on isomerically mixed samples. We demonstrate the technique on cis/trans 1,2-dibromoethene (C2H2Br2). The momentum correlation between the bromine ions in a three-body fragmentation process induced by bromine 3d inner-shell photoionization is used to identify the cis and trans structures of the isomers. The experimentally determined momentum correlations and the isomer-resolved fragment-ion kinetic energies are matched closely by a classical Coulomb explosion model. | |
dc.identifier.uri | http://hdl.handle.net/2097/38456 | |
dc.relation.uri | https://doi.org/10.1038/srep38202 | |
dc.rights | Attribution 4.0 International (CC BY 4.0) | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.subject | Photoactive Yellow Protein | |
dc.subject | 3-Body Dissociations | |
dc.subject | Gas-Phase | |
dc.subject | Dynamics | |
dc.subject | Isomerization | |
dc.subject | Configuration | |
dc.title | Identification of absolute geometries of cis and trans molecular isomers by Coulomb Explosion Imaging | |
dc.type | Article |
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